DOI: https://doi.org/10.31319/2519-8106.2(41)2019.185060

MODEL OF THE MECHANISM REACTION FOR HYDROCARBONS ON INTERMETALLIC CATALYSTS

Борис Петрович Середа, Карина Володимирівна Бєлоконь, Юрій Олександрович Бєлоконь, Дмитро Олегович Кругляк, Дмитро Борисович Середа

Анотація


The kinetic characteristics oxidation processes of propane on an intermetallic catalyst of the composition Ni-Co-Mn-Cu-Al are determined. On the basis of the modified model of Mars-Van Crevelin, effective reaction rate constants and activation energies were obtained. For the oxidation of propane on a Ni-Al-Co-Mn-Cu catalyst, the activation energy is 65.5 kJ/mol, which is 1.2 times lower than the activation energy of Ni-Al alloys.

Ключові слова


intermetallic catalyst; Mars-Van Crevelen model; reaction rate constant; activation energy

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Посилання


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ISSN 2519-8106 (Print), eISSN 2519-8114 (Online)